Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Effects of amino functionality on uptake of CO2, CH4 and selectivity of CO2/CH4 on titanium based MOFs
Zana Hassan Rada,Hussein Rasool Abid,Jin Shang,Yingdian He,Paul A. Webley,Shaomin Liu,Hongqi Sun,Shaobin Wang +7 more
TL;DR: In this paper, the effects of double linkers in the synthesis process and addition of amino-functionalised linker in the structure on adsorption of CO2 and CH4 have been discussed.
Journal ArticleDOI
Research trend of metal---organic frameworks: a bibliometric analysis
Chong-Chen Wang,Yuh-Shan Ho +1 more
TL;DR: A bibliometric analysis based on the related articles in the Science Citation Index Expanded database was conducted to gain insight into global trends and hot issues of metal–organic frameworks (MOFs), finding that adsorption took the lead, followed by catalysis, as a result of their ultrahigh porosity and even their catalytic property.
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Mixed matrix membranes incorporated with cubic-MOF-5 for improved polyetherimide gas separation membranes: Theory and experiment
Mehrzad Arjmandi,Majid Pakizeh +1 more
TL;DR: In this paper, the structure of C-MOF-5 nanocrystals was characterized by XRD, FTIR, particle size analysis, and N2 adsorption techniques.
Journal ArticleDOI
Hierarchical MOF-xerogel monolith composites from embedding MIL-100(Fe,Cr) and MIL-101(Cr) in resorcinol-formaldehyde xerogels for water adsorption applications
TL;DR: In this paper, micro-to-mesoporous MIL-100(Fe,Cr) and MIL-101(Cr) composites were synthesized using a mesoporous resorcinol-formaldehyde based xerogel as binding agent.
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Enhancing the Water Stability of Al-MIL-101-NH2 via Postsynthetic Modification
TL;DR: A remarkable stabilisation of the mesoporous MOF Al-MIL-101-NH2 by postsynthetic modification with phenyl isocyanate, which favours a shielding mechanism of the Al clusters by the pendant phenyl groups and rules out pore blocking.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.