Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
Citations
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Application of ZIF-8–graphene oxide sponge to a solid phase extraction method for the analysis of sex hormones in milk and milk products by high-performance liquid chromatography
TL;DR: In this article, a zeolitic imidazolate framework-8 (ZIF-8) incorporating a graphene oxide sponge (GOS) nanocomposite was synthesized successfully by a simple one-pot preparation method.
Journal ArticleDOI
Metal-organic frameworks as advanced sorbents for oil/water separation
Mozhgan Shahmirzaee,Jafar Abdi,Abdolhossein Hemmati-Sarapardeh,Mahin Schaffie,Mohammad Ranjbar,Alireza Khataee +5 more
TL;DR: In this paper , a review of the recent applications of metal-organic frameworks (MOFs) with different morphologies and chemical compositions for oil/water separation is presented, and a comparison of the MOF materials as a hydrophobic platform and removal methods for oil sorption are presented.
Journal ArticleDOI
X-ray Structure and Magnetic Properties of Heterobimetallic Chains Based on the Use of an Octacyanidodicobalt(III) Complex as Metalloligand
Maria-Gabriela Alexandru,Diana Visinescu,Sergiu Shova,Abdeslem Bentama,Francesc Lloret,Joan Cano,Miguel Julve +6 more
TL;DR: In this paper, the assembly of [Co2III(μ-2,5-dpp)(CN)8]2− anions and [MII(CH3OH)2(DMSO)2+ cations resulted into the formation of two heterobimetallic 1D coordination polymers.
Journal ArticleDOI
Design and synthesis of novel ditopic ligands with a pyrazole ring in the central unit
Bogdan-Ionel Bratanovici,Alina Nicolescu,Sergiu Shova,Ioan-Andrei Dascălu,Rodinel Ardeleanu,Vasile Lozan,Gheorghe Roman +6 more
TL;DR: In this article, four ditopic ligands that have a pyrazole ring in their central unit and are useful for the generation of coordination polymers have been synthesized, and the structure of the intermediates and of the target ligands has been investigated by solution NMR, special attention being given to keto-enol and pyrazoles tautomerism when present.
Journal ArticleDOI
Coordination polymers based on 1,1′-cobaltocenium dicarboxylate linkers
TL;DR: In this article, the structural relationships between two-dimensional coordination polymers and the dependence on type and quantity of cocrystallized solvent molecules are discussed in the presence of 4,4′-bipyridine (bipy) as a co-linker.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.