Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Construction of six non-covalent-bonded supramolecules from reactions of cadmium(II), and zinc(II) with 3,5-dimethylpyrazole and carboxylate ligands
Shouwen Jin,Daqi Wang +1 more
TL;DR: In this paper, the X-ray studies revealed that these complexes display mononuclear to trinuclear structures with tetrahedral geometry around each zinc center and octahedral geometry surrounding each cadmium ion, and the extensive nonbonding interactions in these compounds are responsible for different structures such as 3D network, 2D sheet, and 3D layer network structure.
Journal ArticleDOI
A 3D In(III) coordination polymer derived from rigid dicarboxylate ligand: Synthesis, crystal structure and catalytic property
TL;DR: In this article, a new indium coordination polymer, In(OH)(H2O)(1,4-bdc) (1 4-H2BDc) = 1, 4-benzendicarboxylic acid), has been prepared under solvothermal conditions using a mixture of rigid organic linker and inorganic heteropolyacid (12-phosphotungstic acid) template.
Journal ArticleDOI
Template effect of innocent and coordinating anions on the formation of interpenetrated 2D and 3D networks: methyl orange and iodine sorption studies
TL;DR: In this paper, a 3D Cd(II) coordination polymer was synthesized with 2,5-bis(4-pyridyl)-3,4-diaza-2,4hexadiene (L1) while the use of benzene-1,3-disulphonate (L2) along with L1 resulted in a novel 3D coordination polymer, [Cd(L 1)2(L2)]·2(H2O)·(CH3OH), CP2.
Journal ArticleDOI
A supramolecular dual-host based ion-pair induced formation of 1D coordination polymer
TL;DR: An N-bridged tripodal urea receptor (L1) in combination with 18crown-6-ether (LC) has been structurally authenticated to self-assemble into an integrated 1D coordination polymer in the presence of potassium carbonate (K2CO3) as mentioned in this paper.
Journal ArticleDOI
Molecular simulations of adsorption and separation of ethylene/ethane and propylene/propane mixtures on Ni2(dobdc) and Ni2(m-dobdc) metal-organic frameworks
Mohammad Gholami,Saeid Yeganegi +1 more
TL;DR: In this paper, the authors studied porous solid adsorbents as a promising alternative to the traditional cryogenic distillation for separating olefin/paraffin mixtures.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.