Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Sandwich-type Inorganic–Organic Hybrid Solids of Iso-polyvanadate Clusters and Decamethylcucurbit[5]uril
Li-Wei Han,Li-Wei Han,Jing-Xiang Lin,Jing-Xiang Lin,Qi Yin,Qi Yin,Bahar Karadeniz,Hongfang Li,Jian Lu,Rong Cao +9 more
TL;DR: In this article, three sandwich-type inorganic-organic hybrid solids based on iso-polyvanadate (POM)-clusters were synthesized under hydrothermal conditions.
Journal ArticleDOI
Structural Diversity of Metallosupramolecular Assemblies from Cu(phen)2+ (phen = 1,10‐Phenanthroline) Building Blocks and 4,4′‐Bipyridine
TL;DR: Du et al. as mentioned in this paper used a single-crystal X-ray analysis at 296 and 110 K to determine the crystal structure of 4,4′-bipyridine.
Journal ArticleDOI
Stimulus-responsive reversible thermochromism and exciplex emission of a Zn(ii) complex and selective sensing of NH3 gas.
TL;DR: A thermally induced redox reaction occurred in the charge transfer of complex 1 giving rise to a persistent radical species which shows fast response and high selectivity toward gaseous NH3 as a solid-state colorimetric and fluorescent bifunctional sensor.
Journal ArticleDOI
Poly(methylvinylsiloxane)-Based High Internal Phase Emulsion-Templated Materials (polyHIPEs)-Preparation, Incorporation of Palladium, and Catalytic Properties.
Jan Mrówka,Mariusz Gackowski,Lidia Lityńska-Dobrzyńska,Andrzej Bernasik,R. Kosydar,Alicja Drelinkiewicz,Magdalena Hasik +6 more
TL;DR: The Pd-containing polyHIPEs showed activity in catalytic hydrogenation of the triple carbon–carbon bond in phenylacetylene giving the unsaturated product, styrene with a selectivity of ca.
Journal ArticleDOI
Investigation on the Interconversion from DMF-Solvated to Unsolvated Copper(II) Pyrazolate Coordination Polymers
Corrado Di Nicola,Alessia Tombesi,Marco Moroni,Rebecca Vismara,Fabio Marchetti,Riccardo Pettinari,Luca Nardo,Guglielmo Vesco,Simona Galli,Silvia Casassa,Luciano Pandolfo,Claudio Pettinari +11 more
TL;DR: In this paper, a series of copper pyrazolates were synthesized employing different synthetic approaches, showing square planar trans-CuN2O2 or octahedral trans-cuN4O2 (2DMF-5DMF) metal centers.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.