Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Journal ArticleDOI
A study on hydrothermal synthesis of metal–organic framework mil-101
Võ Thị Thanh Châu,Hoàng Văn Đức +1 more
TL;DR: In this article, a synthesis of MIL-101 by hydrothermal process was demonstrated and the obtained samples were characterized by powder X-ray diffraction (PXRD), transmission electron microscope (TEM), nitrogen adsorption/desorption isotherms at 77K, X-Ray photoelectron spectroscopy (XPS).
Book ChapterDOI
Metal-organic frameworks and exemplified cytotoxicity evaluation
TL;DR: A review of porous materials demonstrates that the synergy of metal centers and coordination networks facilitates structure to function applications such as gas storage, catalysis, diagnosis and therapy, and energy generation as mentioned in this paper.
Journal ArticleDOI
Exploring the Intense Lanthanide Luminescence and High Thermal Stability in a New Mixed Eu3+/Tb3+ Organic Framework Series for Marking in Gunshot Residues
Julia P. De Oliveira Silva,M.V. Colaço,Leonardo A. De Souza,Molíria V. dos Santos,Roberta S. Pugina,Lippy F. Marques +5 more
Journal ArticleDOI
Two Manganese(II) Complexes with a Bulky Fluorene-Based Carboxylate Ligand: Syntheses, Crystal Structures, and Luminescent Properties
TL;DR: In this article, two manganese-II complexes with 9,9-dibutyl-9H- fluorene-2,7-carboxylate (L) were synthesized and characterized.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.