Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Luminescent Functional Metal–Organic Frameworks
Journal ArticleDOI
Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites.
Norbert Stock,Shyam Biswas +1 more
Journal ArticleDOI
Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks
Jian-Rong Li,Yuguang Ma,M. Colin McCarthy,Julian P. Sculley,Jiamei Yu,Hae-Kwon Jeong,Perla B. Balbuena,Hong-Cai Zhou +7 more
TL;DR: In this article, the authors review the research progress in metal-organic frameworks (MOFs) for CO 2 adsorption, storage, and separations that are directly related to CO 2 capture.
Journal ArticleDOI
Metal Azolate Frameworks: From Crystal Engineering to Functional Materials
TL;DR: A comparison study of 3D Networks Based on Polypyrazolates, Metal 1,2,4-Triazolate Frameworks, and Univalent Coinage-Metal Tetrazolate Framework 1025.
Journal ArticleDOI
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions
TL;DR: In this review, the applications of MOFs with multiple active sites in synergistic organic catalysis, photocatalysis and tandem reactions are discussed and proposed mechanisms are presented in detail.
References
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Heterogeneous Asymmetric Catalysis with Homochiral Metal–Organic Frameworks: Network-Structure-Dependent Catalytic Activity
Chuan-De Wu,Wenbin Lin +1 more
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Oriented Growth of the Metal Organic Framework Cu3(BTC)2(H2O)3·xH2O Tunable with Functionalized Self-Assembled Monolayers
TL;DR: The tunable oriented growth of thin films of the porous framework HKUST-1 (Cu3(C9H3O6)2(H2O)3·xH2 O) on different functionalized self-assembled monolayers (SAMs) is demonstrated and the morphological evolution of the crystalline phases is followed.
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Metal Nuclearity Modulated Four‐, Six‐, and Eight‐Connected Entangled Frameworks Based on Mono‐, Bi‐, and Trimetallic Cores as Nodes
TL;DR: Detailed structural comparison of these complexes indicates that the increase in metal nuclearity induces the progressive increase in the connectivities of the ultimate nets: that is, the metalnuclearity plays a significant role in tuning the connectivity of a specific network.
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Catalytic properties of MIL-101
TL;DR: A very high catalytic activity in the cyanosilylation reaction was observed for MIL-101, a chromium based metal-organic framework, which is a remarkably stable support for palladium in hydrogenation reactions, with significantly higher activity than e.g. palladium on activated carbon.
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Cyano-Bridged Re6Q8 (Q = S, Se) Cluster-Cobalt(II) Framework Materials: Versatile Solid Chemical Sensors
TL;DR: In this paper, face-capped octahedral clusters of the type [Re6Q8(CN)6]4- (Q = S, Se) are used to space apart partially hydrated Co2+ ions in extended solid frameworks, creating porous materials that display dramatic color changes upon exposure to certain organic solvents.