Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Journal ArticleDOI
Calix[4]arene-based metal–organic frameworks: towards hierarchically porous materials
Sean P. Bew,Andrew D. Burrows,Tina Düren,Mary F. Mahon,Peyman Z. Moghadam,Viorica M. Sebestyen,Sean M. Thurston +6 more
TL;DR: An upper rim-functionalised calix[4]arene dicarboxylic acid has been used to prepare four metal-organic frameworks, three of which have been structurally characterised and shown to form two- or three-dimensional network structures.
Journal ArticleDOI
Carboranes as guests, counterions and linkers in coordination polymers and networks
TL;DR: Carborane clusters play a variety of roles in the assembly of 1D-coordination polymers and 2D-and 3D-networks as discussed by the authors, and carborane guests are accommodated in the backbones of coordination polymers.
Journal ArticleDOI
Recent Innovation of Metal-Organic Frameworks for Carbon Dioxide Photocatalytic Reduction.
TL;DR: In this review, recent MOF headway is presented focusing on reports of the last three years, exhaustively categorized based on central metal-type, and novel discussion, from material preparation to photocatalytic, simulated performance recordings of respective as-synthesized materials.
Journal ArticleDOI
Atypical stoichiometry for a 3D bimetallic oxalate-based long-range ordered magnet exhibiting high proton conductivity
Catalin Maxim,Sylvie Ferlay,Sylvie Ferlay,Hiroko Tokoro,Shin-ichi Ohkoshi,Cyrille Train,Cyrille Train,Cyrille Train +7 more
TL;DR: The reproducible formation of a 3D oxalate based coordination compound of formula (NH4)5[Mn(II)2Cr( III)3(ox)9]·10H2O, with an unusual Mn(II)/Cr(III) ratio, is presented.
Journal ArticleDOI
Sustainable Synthesis of MOF-5@GO Nanocomposites for Efficient Removal of Rhodamine B from Water.
TL;DR: In this paper, a metal-organic framework (MOF-5) is synthesized by a solvothermal process and graphene oxide (GO) is prepared from the improved Hummer method.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.