Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
Citations
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Sonochemical syntheses of two new flower-like nano-scale high coordinated lead(II) supramolecular coordination polymers
TL;DR: 1D double chains of compounds 1 and 2 further extended into two-dimensional (2D) and three dimensional (3D) supramolecular structures by strong π-π directional intermolecular interactions, respectively.
Journal ArticleDOI
High-throughput screening of metal – Organic frameworks for CO2 and CH4 separation in the presence of water
Justyna Rogacka,Agnieszka Seremak,Azahara Luna-Triguero,Filip Formalik,I. Matito-Martos,Lucyna Firlej,Lucyna Firlej,Sofia Calero,Sofia Calero,Bogdan Kuchta,Bogdan Kuchta +10 more
TL;DR: In this article, a large-scale computational screening was applied to identify metal-Organic Frameworks (MOFs) structures which exhibit high CO2/CH4 selectivity and total loading higher than 0.5 mol/kg (in the presence of water).
Journal ArticleDOI
Incorporation by coordination and release of the iron chelator drug deferiprone from zinc-based metal–organic frameworks
Andrew D. Burrows,Monika Jurcic,Luke L. Keenan,Rebecca A. Lane,Mary F. Mahon,Mark R. Warren,Harriott Nowell,Michael Paradowski,John Spencer +8 more
TL;DR: A series of new zinc-based metal-organic framework materials has been prepared in which deferiprone is incorporated as a chelating ligand on infinite or tri-zinc secondary building units following deprotonation.
Journal ArticleDOI
Identification of a robust and reproducible noncluster-type SBU: effect of coexistent groups on network topologies, helicity, and properties
TL;DR: In this paper, a series of Zn(II) coordination polymers using a tailor-made SBU, designed with the proper utilization of the hydrogen bonds of a pyrazole-based ligand 4,4′-methylene-bispyrazole (H2MBP), and its derivatives (R-H2IPA; R = OH, OCH3, CH3, tBu, Br, I, NH2, N3).
Journal ArticleDOI
An Interwoven Metal-Organic Framework Combining Mechanically Interlocked Linkers and Interpenetrated Networks
TL;DR: The interlocked hexadentate ligand forms the first example of a new type of lattice containing interwoven frameworks resulting from both interpenetration of frameworks due to the presence of an interlocked ligand and more classical interpenetsration of independent frameworks.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.