Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
Citations
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Clathrochelate-based bipyridyl ligands of nanoscale dimensions: easy-to-access building blocks for supramolecular chemistry
TL;DR: Boronic acid-capped clathrochelates were used to build rigid, linear bipyridyl ligands with adjustable lengths between 1.5 and 5.4 nm.
Journal ArticleDOI
Design of metal-organic frameworks (MOFs)-based photocatalyst for solar fuel production and photo-degradation of pollutants
TL;DR: In this paper, the design factors of photocatalytic materials based on MOFs from the perspective of a star MOF were summarized, and the modification strategies of MOFs-based photocatalyst were discussed.
Journal ArticleDOI
Recent Advances in the Use of Metal-Organic Frameworks for Dye Adsorption.
TL;DR: In this mini review, the recent advances in the use of MOFs for the adsorption of organic dyes will be summarized.
Journal ArticleDOI
Additive-mediated size control of MOF nanoparticles
Annekathrin Ranft,Annekathrin Ranft,Sophia B. Betzler,Frederik Haase,Frederik Haase,Bettina V. Lotsch,Bettina V. Lotsch +6 more
TL;DR: In this paper, a fast synthesis approach for sub-60 nm sized MOF nanoparticles was developed by employing auxiliary additives and control over the size of HKUST-1 and IRMOF-3 particles was gained by adjusting the concentration and type of stabilizers.
Journal ArticleDOI
Molecular Factors Controlling the Isomerization of Azobenzenes in the Cavity of a Flexible Coordination Cage
TL;DR: Molecular models are employed to reconstruct the mechanism of azobenzene switching inside the cage cavity and explore key molecular factors that may control this event, which may enable the rational design of photoswitchable systems whose reactivity can be controlled via host–guest interactions.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.