Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
Citations
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Journal ArticleDOI
Enhanced Oral Bioavailability of the Pharmacologically Active Lignin Magnolol via Zr-Based Metal Organic Framework Impregnation.
Joshua H. Santos,Mark Tristan J. Quimque,Mark Tristan J. Quimque,Allan Patrick G. Macabeo,Mary Jho-Anne T Corpuz,Yun-Ming Wang,Tsai-Te Lu,Chia Her Lin,Oliver B. Villaflores +8 more
TL;DR: Unconjugated magnolol was found in the liver, kidney, and brain of rats in all treatment groups and Uio-66(Zr) provided a higher Magnolol bioavailability when used as drug carrier.
Journal ArticleDOI
BGO/AlFu MOF core shell nano-composite based bromide ion-selective electrode
TL;DR: In this paper, a core shell nano-composite based on boron doped graphene oxide-aluminium fumarate metal organic framework (BGO/AlFu MOF) has been reported for fabrication of bromide ion selective electrode (ISE).
Journal ArticleDOI
A crystalline and free-standing silver thiocarboxylate thin-film showing high green to yellow luminescence
Javier Troyano,Oscar Castillo,Pilar Amo-Ochoa,Vanesa Fernández-Moreira,Carlos J. Gómez-García,Félix Zamora,Salomé Delgado +6 more
TL;DR: In this paper, the simple direct synthesis of Cu(II) and Ag(I) salts and thiobenzoic acid under ambient conditions allows the preparation of two bidimensional coordination polymers [M(TB)]n (TB = thibenzoate; M = Cu (1) or Ag (2)).
Book ChapterDOI
Adsorption by Metal-Organic Frameworks
TL;DR: In this article, the effect of changing a given feature of the MOFs (ligand length, functionalisation, metal node, flexibility, etc.) on their adsorption properties is explored.
Journal ArticleDOI
Group IIB metal complexes with a multidentate N-donor tecton 3,4-bis(2-pyridyl)-5-(3-pyridyl)-1,2,4-triazole: Metal-directed assemblies, crystal structures and properties
TL;DR: In this article, a 2D layered coordination polymer constructed from the linkage of [Zn3(μ-Cl)2] trinuclear units by L4 spacers is presented.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.