Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Luminescent Functional Metal–Organic Frameworks
Journal ArticleDOI
Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites.
Norbert Stock,Shyam Biswas +1 more
Journal ArticleDOI
Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks
Jian-Rong Li,Yuguang Ma,M. Colin McCarthy,Julian P. Sculley,Jiamei Yu,Hae-Kwon Jeong,Perla B. Balbuena,Hong-Cai Zhou +7 more
TL;DR: In this article, the authors review the research progress in metal-organic frameworks (MOFs) for CO 2 adsorption, storage, and separations that are directly related to CO 2 capture.
Journal ArticleDOI
Metal Azolate Frameworks: From Crystal Engineering to Functional Materials
TL;DR: A comparison study of 3D Networks Based on Polypyrazolates, Metal 1,2,4-Triazolate Frameworks, and Univalent Coinage-Metal Tetrazolate Framework 1025.
Journal ArticleDOI
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions
TL;DR: In this review, the applications of MOFs with multiple active sites in synergistic organic catalysis, photocatalysis and tandem reactions are discussed and proposed mechanisms are presented in detail.
References
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Journal ArticleDOI
Crystal engineering of coordination polymers using 4,4′-bipyridine as a bond between transition metal atoms
TL;DR: The role of 4,4'-bipyridine in discovering various coordination polymers with novel topologies that range from one-dimensional to three dimensional are described.
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A route to the synthesis of trivalent transition-metal porous carboxylates with trimeric secondary building units.
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Molecular building blocks approach to the assembly of zeolite-like metal–organic frameworks (ZMOFs) with extra-large cavities
TL;DR: Two novel porous anionic zeolite-like metal-organic frameworks have been synthesized by metal-ligand-directed assembly of rigid and directional tetrahedral building units, InN4 synthesized in situ, and doubly deprotonated bis(bidentate) imidazoledicarboxylic acid ligands (HImDC) in the presence of different structure directing agents (SDAs).
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High-throughput assisted rationalization of the formation of metal organic frameworks in the Iron(III) aminoterephthalate solvothermal system.
Sebastian Bauer,Christian Serre,Thomas Devic,Patricia Horcajada,Jérôme Marrot,Gérard Férey,Norbert Stock +6 more
TL;DR: It is found that the nature of the reaction medium has the most profound impact on structure formation and the concentration of the starting mixture and the temperature have also been identified as key parameters for the formation of the different hybrid phases.
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Magnetic nanoporous coordination polymers
TL;DR: The use of organic molecules as an alternative strategy for achieving new nanoporous metal-organic materials has become an attractive prospect as mentioned in this paper, and the use of transition metal ions opens the possibility to obtain nanoporous materials with additional electrical, optical or magnetic properties.