Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Guest effect on nanopatterned spin-crossover thin films.
Carlos Bartual-Murgui,Amal Akou,Lionel Salmon,Gábor Molnár,Christophe Thibault,José Antonio Real,Azzedine Bousseksou +6 more
TL;DR: The interplay between host-guest and spin-crossover properties in thin films and nanopatterns demonstrates the potential ability of using this kind of material as a microsensor.
Journal ArticleDOI
Porous molecular crystals by macrocyclic coordination supramolecules.
Irene Bassanetti,Angiolina Comotti,Piero Sozzani,Silvia Bracco,Gianluca Calestani,Francesco Mezzadri,Luciano Marchiò +6 more
TL;DR: This study shows how the combination of metal ions, counter-anions and opportunely functionalized and preorganized ligands gives rise to two distinct supramolecular isomers, coordination polymeric chains and hexameric macrocycles.
Journal ArticleDOI
A hybrid material composed of reduced graphene oxide and porous carbon prepared by carbonization of a zeolitic imidazolate framework (type ZIF-8) for voltammetric determination of chloramphenicol
TL;DR: The method has a wide scope in that it may be applied to the preparation of various kinds of other (doped) porous carbon/rGO composites for use in (bio)chemical sensors.
Journal ArticleDOI
Synthesis, structure, magnetic properties and EPR spectroscopy of a copper(II) coordination polymer with a ditopic hydrazone ligand and acetate bridges
Rahman Bikas,Rahman Bikas,Pavlo Aleshkevych,Hassan Hosseini-Monfared,Joaquín Sanchiz,R. Szymczak,Tadeusz Lis +6 more
TL;DR: The EPR and magnetic susceptibility measurements confirm the existence of two kinds of Cu(II) dimers and the ditopic isonicotinhydrazone ligand coordinates to the Cu1 center through the N2O-donor set and connects to theCu2 center by a pyridine group of the isonicotine part.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.