Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
Citations
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Intramolecular fixation of t-butyl groups in thiolactim ethers influencing molecular conformation and the packing behavior
TL;DR: In this article, the formation of the intramolecular hydrogen bonding motif has not only impact on the molecular stability but in some cases also predictably influences the reactivity and the packing behavior of the different heterocycles.
Dissertation
RGD-Based Metal Organic Frameworks For Selective Delivery Of Therapeutics To Tumour Vasculature
TL;DR: Dissertacao de mestrado integrado as mentioned in this paper in Bioengenharia. Faculdade de Engenharias, Universidade do Porto. 2012
Journal ArticleDOI
Metal–organic framework detectives meet infectious pathogens: A powerful tool against pandemics
TL;DR: In this paper , a review of the recent progress of metal-organic frameworks (MOFs) based biosensors for pathogen detection in colorimetric, fluorescent, electrochemical and other methods is comprehensively reviewed.
Journal ArticleDOI
From Catalyst Structure Design to Electrode Fabrication of Platinum-free Electrocatalysts in Proton Exchange Membrane Fuel Cells: A Review
Wulandhari Sudarsono,Sue Ying Tan,Wai-Yin Wong,Fatin Saiha Omar,K.C. Ramya,Shahid Mehmood,Alaek Nu’man,Rashmi Walvekar,Mohammad Waqas Khalid +8 more
TL;DR: In this paper , the impacts of the non-PGM catalyst structure on the ORR activity and single-cell performance are presented. But, due to macroscale degradation and flooding issues in fuel cell systems, catalyst development has faced significant challenges in rapid active site degradation over a short time.
Journal ArticleDOI
Enhanced Solid-State Fluorescence of Flavin Derivatives by Incorporation in the Metal-Organic Frameworks MIL-53(Al) and MOF-5
Dietrich Püschel,Simon Hédé,Iván Maisuls,Simon-P. Höfert,Dennis Woschko,Ralf Kühnemuth,Suren Felekyan,Claus A. M. Seidel,Constantin Czekelius,Oliver Weingart,Cristian A. Strassert,Christoph Janiak +11 more
TL;DR: In this paper , the authors used a post-synthetic, diffusion-based incorporation into microcrystalline MIL-53 powders with one-dimensional (1D) pores and an in-situ approach during the synthesis of MOF-5 with its 3D channel network.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.