Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
Citations
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Journal ArticleDOI
Study of the Dye Adsorption Kinetics of Metal–Organic Frameworks in Aqueous Media
Journal ArticleDOI
2D Porous Honeycomb Polymers versus Discrete Nanocubes from Trigonal Trinuclear Complexes and Ligands with Variable Topology
Victoria N. Dorofeeva,Sergey V. Kolotilov,Mikhail A. Kiskin,Ruslan A. Polunin,Zhanna V. Dobrokhotova,Olivier Cador,Stéphane Golhen,Lahcène Ouahab,Igor L. Eremenko,Vladimir M. Novotortsev +9 more
TL;DR: Analysis of possible structures that could be assembled from these building blocks showed that compounds 1 and 2 corresponded to their respective predicted topologies.
Journal ArticleDOI
Multimetallic Complexes and Functionalized Gold Nanoparticles Based on a Combination of d- and f-Elements
Simon Sung,Holly E. Holmes,Luke Wainwright,Anita Toscani,Graeme J. Stasiuk,Andrew J. P. White,Jimmy D. Bell,James D. E. T. Wilton-Ely +7 more
TL;DR: The new DO3A-derived dithiocarbamate ligand is formed by treatment of the ammonium salt [DO3A-(t)Bu]HBr with K2CO3 and carbon disulfide and can be used to prepare gold nanoparticles, Au@S2C-DO3 a-Bu, by displacement of the surface units from citrate-stabilized nanoparticles.
Journal ArticleDOI
Halloysite nanotubes based heterogeneous solid acid catalysts
Aman Mahajan,Princy Gupta +1 more
TL;DR: In this article, a review article is presented to unveil the research on halloysite nanotubes for the preparation of solid acids and their applications in acid catalytic processes, and the main focus of the review is on the application of the nanostructures with synergistic catalytic effects.
Journal ArticleDOI
A New Coordination Polymer Exhibiting Unique 2D Hydrogen‐Bonded (H2O)16 Ring Formation and Water‐Dependent Luminescence Properties
Chih-Chieh Wang,Ching-Chun Yang,Wen-Chun Chung,Gene-Hsiang Lee,Mei-Lin Ho,Ya-Chien Yu,Min-Wen Chung,Hwo-Shuenn Sheu,Chien-Hung Shih,Kum-Yi Cheng,Pei-Jen Chang,Pi-Tai Chou +11 more
TL;DR: Powder X-ray analyses reveal that the dehydration process induces the readjustment of dpe π-π stacking distance/orientation, which results in dramatic luminescence changes from dim pale blue to bright white-light generation upon water depletion, accompanied by a ≈100-fold increase in the emission intensity.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.