Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
Citations
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Solvent-Induced Structural Diversity of Partially Fluorinated, Stable Pb(II) Metal–Organic Frameworks and Their Luminescence Properties
TL;DR: In this article, a linear partially fluorinated ligand 2,2′-bis-trifluoromethyl-biphenyl-4,4′-dicarboxylic acid (H2L) was synthesized and used to construct five metal organic frameworks with Pb(II) through hydro-and solvothermal techniques.
Journal ArticleDOI
Improved ethanol recovery through mixed-matrix membrane with hydrophobic MAF-6 as filler
Qianqian Li,Long Cheng,Jie Shen,Jiayan Shi,Guining Chen,Jing Zhao,Jingui Duan,Gongping Liu,Wanqin Jin +8 more
TL;DR: In this article, the superhydrophobic alkyl group modificated metal organic framework (MAF-6) was incorporated into polydimethylsiloxane (PDMS) polymer to fabricate mixed matrix membranes (MMMs).
Journal ArticleDOI
A Porous Cobalt Tetraphosphonate Metal–Organic Framework: Accurate Structure and Guest Molecule Location Determined by Continuous‐Rotation Electron Diffraction
Bin Wang,Timo Rhauderwiek,A. Ken Inge,Hongyi Xu,Taimin Yang,Zhehao Huang,Norbert Stock,Xiaodong Zou +7 more
TL;DR: It is demonstrated for the first time that organic molecules in the pores of the MOF framework could be located using the cRED data, and a comparison of eight independent structure determinations using different datasets shows that structural models differ only on average by 0.03(2) Å.
Journal ArticleDOI
[WS4Cu3I2]− and [WS4Cu4]2+ secondary building units formed a metal–organic framework: Large tubes in a highly interpenetrated system
TL;DR: A 3D metal-organic framework that contains four anionic and four cationic frameworks formed by tetranuclear and pentanuclear SBUs with long dpbp ligands is presented, which contains large rhombus-shaped tubes with diagonal dimensions.
Journal ArticleDOI
New forms of old drugs: improving without changing
Sofia Domingos,Vânia André,Vânia André,Sílvia Quaresma,Inês C. B. Martins,M. Fátima M. Piedade,M. Fátima M. Piedade,Maria Teresa Duarte +7 more
TL;DR: In a short approach, the improvements that have recently been done in the world of new solid forms of known active pharmaceutical ingredients (APIs) are presented.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.