Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Kühlen mit Sonnenlicht
TL;DR: In Deutschland verbrauchen Kalte-and Klimaanlagen etwa 14 Prozent der jahrlichen elektrischen endenergie.
Journal ArticleDOI
Biomass@MOF-Derived Carbon Aerogels with a Hierarchically Structured Surface for Treating Organic Pollutants
TL;DR: Porous carbon materials are highly attractive in the research field of adsorption, particularly for treating organic pollutants in wastewater, of which the facile yet generic methods is highly pur... as mentioned in this paper.
Journal ArticleDOI
Structural insights into coordination polymers based on 6s2 Pb(II) and Bi(III) centres connected via heteroaromatic carboxylate linkers and their potential applications
TL;DR: In this paper, a comprehensive review of the literature on coordination polymers is presented, focusing on three main topics concerning Pb(II) and Bi(III) polymers: i) coordination modes of linkers, ii) central ion lone electron pair stereoactivity, iii) topology, and potential applications.
Journal ArticleDOI
Photonic gratings of the metal-organic framework {Fe(bpac)[Pt(CN)4]} with synergetic spin transition and host-guest properties.
Amal Akou,Carlos Bartual-Murgui,Khaldoun Abdul-Kader,Manuel Lopes,Gábor Molnár,Christophe Thibault,Christophe Vieu,Lionel Salmon,Azzedine Bousseksou +8 more
TL;DR: While the grating thickness had no influence on the spin-crossover properties of the gratings, the adsorption of aromatic guest molecules was found to have a substantial effect both on thespin transition temperature and the completeness of the transition.
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Simple low cost porphyrinic photosensitizers for large scale chemoselective oxidation of sulfides to sulfoxides under green conditions: targeted protonation of porphyrins
Aida G. Mojarrad,Saeed Zakavi +1 more
TL;DR: In this article, the solvent effect on the efficiency of the sulfide photooxidation reaction was investigated using acetonitrile, 1,2-dichloroethane (DCE) and toluene.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.