Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Ambient pressure synthesis of MIL-100(Fe) MOF from homogeneous solution using a redox pathway
TL;DR: This contribution presents a method to synthesize crystalline fluoride-free MIL-100(Fe) from iron(iii) nitrate and trimesic acid in zeotropic DMSO/water solution at normal ambient pressure involving a D MSO-nitrate redox pathway.
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Designing Multifunctional 5-Cyanoisophthalate-Based Coordination Polymers as Single-Molecule Magnets, Adsorbents, and Luminescent Materials
TL;DR: Interestingly, some crystal structures (three-dimensional frameworks of 4-Ln and 5 and 3D network of 6) exhibit open architectures containing large solvent-occupied void systems, among which 5 reveals permanent porosity as confirmed by N2 adsorption measurements at 77 K.
Journal ArticleDOI
Synthesis of a Zn(II)-based 1D zigzag coordination polymer for the fabrication of optoelectronic devices with remarkably high photosensitivity
Basudeb Dutta,Dhananjoy Das,Joydeep Datta,Angeera Chandra,Srikanta Jana,Chittaranjan Sinha,Partha Pratim Ray,Mohammad Hedayetullah Mir +7 more
TL;DR: In this article, a Zn(II)-based one-dimensional coordination polymer (1D CP), [Zn4(adc)4(4-cltpy)4]·CH3OH·2H2O (1), has been synthesized by a slow diffusion method and characterized by X-ray crystallography.
Journal ArticleDOI
Electrochemiluminescence aptasensor for multiple determination of Hg2+ and Pb2+ ions by using the MIL-53(Al)@CdTe-PEI modified electrode.
Defen Feng,Penghui Li,Xuecai Tan,Yeyu Wu,Fucun Wei,Fangkai Du,Chenhao Ai,Yanni Luo,Quanyou Chen,Heyou Han +9 more
TL;DR: The aptasensor could be used for detecting Hg2+ and Pb2+ in fish and shrimp samples with good recoveries and decreased ECL intensity was observed due to enhanced resonance energy transfer (ERET) and attenuated surface plasmon resonance (SPR).
Journal ArticleDOI
Heteronuclear, mixed-metal Ag(I)-Mn(II) coordination polymers with bridging N-pyridinylisonicotinohydrazide ligands: synthesis, crystal structures, magnetic and photoluminescence properties.
Rahman Bikas,Hassan Hosseini-Monfared,Vera Vasylyeva,Joaquín Sanchiz,Javier Alonso,Jose Manuel Barandiaran,Christoph Janiak +6 more
TL;DR: Variable temperature magnetic susceptibility measurements showed that despite the long distance among the high spin Mn(ii) ions, weak antiferromagnetic coupling takes place through the long NC-Ag-CN bridge.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.