Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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A porous and redox active ferrocenedicarboxylic acid based aluminium MOF with a MIL-53 architecture.
Jannik Benecke,Sebastian Mangelsen,Tobias A. Engesser,Thomas Weyrich,Jannik Junge,Norbert Stock,Helge Reinsch +6 more
TL;DR: The first permanently porous ferrocenedicarboxylate, exhibiting a MIL-53 architecture, was synthesised under mild synthesis conditions at ≤100 °C and after a short reaction time of 90 min, and the crystal structure was determined from powder X-ray diffraction data and the compound shows porosity towards N2 and H2O.
Journal ArticleDOI
A cadmium phenylenediacetate isonicotinate network coordination polymer with new topology via in situ amide cleavage
Jacob W. Uebler,Robert L. LaDuca +1 more
TL;DR: In this article, a 3.4,6-connected trinodal topology with a previously unknown 4,4,4-connected {4.6382}2{426282}{6284} topology was presented.
Journal ArticleDOI
Two metal–organic frameworks sharing the same basic framework show distinct interpenetration degrees and different performances in CO2 catalytic conversion
TL;DR: Two metal-organic frameworks with the same basic framework but different degrees of interpenetration were successfully assembled from the same tetracarboxylate ligand and Cu(II) ions in different solvents, which show remarkably different catalytic activities in CO2 cycloaddition reactions owing to their different pore sizes as discussed by the authors.
Journal ArticleDOI
High performance MIL-101(Cr)@6FDA-mPD and MOF-199@6FDA-mPD mixed-matrix membranes for CO2/CH4 separation.
Alexander Nuhnen,Maximilian Klopotowski,Harold B. Tanh Jeazet,Sara Sorribas,Beatriz Zornoza,Carlos Téllez,Joaquín Coronas,Christoph Janiak +7 more
TL;DR: Permeation tests of a binary CO2/CH4 (50/50) gas mixture showed a remarkable increase of CO2 permeabilities for MIL-101(Cr)@6FDA-mPD and significantly higher selectivities for MOF-199@4,4'-hexafluoroisopropylidene diphthalic anhydride.
Supplementary Materials: A Cadmium Anionic 1-D Coordination Polymer {(Cd(H2O)6)(Cd2(atr)2(µ2-btc)2(H2O)4) 2H2O}n within a 3-D Supramolecular Charge-Assisted Hydrogen-Bonded and π -Stacking Network
TL;DR: In this article, a 3-D supramolecular network of hexaaquacadmium(II)-catena and water molecules was constructed from 4-amino-1,2,4-triazole (atr) from btr, which crystallizes to a mixed-ligand, poly-anionic chain of [Cd2(atr]2(µ2-btc)2(H2O)4]2
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.