Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Luminescent Functional Metal–Organic Frameworks
Journal ArticleDOI
Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites.
Norbert Stock,Shyam Biswas +1 more
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Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks
Jian-Rong Li,Yuguang Ma,M. Colin McCarthy,Julian P. Sculley,Jiamei Yu,Hae-Kwon Jeong,Perla B. Balbuena,Hong-Cai Zhou +7 more
TL;DR: In this article, the authors review the research progress in metal-organic frameworks (MOFs) for CO 2 adsorption, storage, and separations that are directly related to CO 2 capture.
Journal ArticleDOI
Metal Azolate Frameworks: From Crystal Engineering to Functional Materials
TL;DR: A comparison study of 3D Networks Based on Polypyrazolates, Metal 1,2,4-Triazolate Frameworks, and Univalent Coinage-Metal Tetrazolate Framework 1025.
Journal ArticleDOI
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions
TL;DR: In this review, the applications of MOFs with multiple active sites in synergistic organic catalysis, photocatalysis and tandem reactions are discussed and proposed mechanisms are presented in detail.
References
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Journal ArticleDOI
Guest-Dependent Spin Crossover in a Nanoporous Molecular Framework Material
TL;DR: The generation of a host lattice that interacts with exchangeable guest species in a switchable fashion has implications for the generation of previously undeveloped advanced materials with applications in areas such as molecular sensing.
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Coordination polymer networks with O- and N-donors: What they are, why and how they are made
TL;DR: A review on metal ion containing coordination polymer networks is given in this paper, where the authors highlight the current research in the field by giving a short overview on the concept of coordination polymers networks, how and why they are made.
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Dynamic porous properties of coordination polymers inspired by hydrogen bonds
Susumu Kitagawa,Kazuhiro Uemura +1 more
TL;DR: This tutorial review focuses on the hydrogen bonding type arrangements for dynamic porous coordination polymers exhibiting elastic guest accommodations, in contrast to rigid three-dimensional (3-D) frameworks.
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Hydrogen sorption in functionalized metal-organic frameworks.
TL;DR: Five porous metal-organic frameworks based on linking zinc oxide clusters with benzene-1,4-dicarboxylate, naphthalene-2,6-dICarboxyate, 4,5,9,10-tetrahydropyrene- 2,7-divellyate, 2,3,5-6-Tetramethylbenzene-3,3-tris(4-benzoate) or benzene
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Hysteretic adsorption and desorption of hydrogen by nanoporous metal-organic frameworks.
Xuebo Zhao,Bo Xiao,Bo Xiao,Ashleigh J. Fletcher,Ashleigh J. Fletcher,K. Mark Thomas,K. Mark Thomas,Darren Bradshaw,Darren Bradshaw,Matthew J. Rosseinsky,Matthew J. Rosseinsky +10 more
TL;DR: It is observed that hysteresis in their adsorption and desorption kinetics above the supercritical temperature of H2 that reflects the dynamical opening of the “windows” between pores, which would allow H2 to be adsorbed at high pressures but stored at lower pressures.