Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
Citations
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Eight Zn(II) coordination networks based on flexible 1,4-di(1H-imidazol-1-yl)butane and different dicarboxylates: crystal structures, water clusters, and topologies
TL;DR: Eight new Zn(II) coordination polymers based on flexible 1,4-di(1H-imidazol-1-yl)butane and different dicarboxylates have been synthesized and structurally characterized by single-crystal X-ray diffraction analyses, which indicates the linkage of central metal ion, the conformation of dimb and dicARboxylate have important influences on the resulting structures.
Journal ArticleDOI
Homochiral lanthanoid(III) mesoxalate metal–organic frameworks: synthesis, crystal growth, chirality, magnetic and luminescent properties
Beatriz Gil-Hernández,Jana K. Maclaren,Henning A. Höppe,Jorge Pasán,Joaquín Sanchiz,Christoph Janiak +5 more
TL;DR: The achiral chelating and bridging mesoxalato ligand (H2mesox2−), the conjugate base of dihydroxymalonic acid (H4mesox), is a new enantiopurity enforcer in extended structures by yielding the Λ/Δ-metal configured homochiral MOFs 2D-[Ln2(μ-H2 mesox)3(H2O)6], [with Ln(III) = La (1), Ce (2), Pr (3), Nd
Journal ArticleDOI
Topologically Unique Heterometallic CuII/Li Coordination Polymers Self-Assembled from N,N-bis(2-Hydroxyethyl)-2-aminoethanesulfonic Acid Biobuffer: Versatile Catalyst Precursors for Mild Hydrocarboxylation of Alkanes to Carboxylic Acids
Marina V. Kirillova,Alexander M. Kirillov,André N. C. Martins,Claudia Graiff,Antonio Tiripicchio,Armando J. L. Pombeiro +5 more
TL;DR: The facile aqueous medium reactions of copper(II) nitrate with BES biobuffer gave rise to the self-assembly generation of three new heterometallic Cu(II)/Li materials, which were isolated as air-stable crystalline solids and fully characterized by infrared (IR) and UV-vis spectroscopy and electrospray ionization (ESI)-MS(±), elemental, thermal, and single-crystal X-ray diffraction analyses.
Journal ArticleDOI
Light-induced changes in magnetism in a coordination polymer heterostructure, Rb0.24Co[Fe(CN)6]0.74@K0.10Co[Cr(CN)6]0.70·nH2O and the role of the shell thickness on the properties of both core and shell.
Olivia N. Risset,Pedro A. Quintero,T. V. Brinzari,Matthew J. Andrus,Michael W. Lufaso,Mark W. Meisel,Daniel R. Talham +6 more
TL;DR: Light-induced changes in the magnetization of the normally light-insensitive KCoCr shell exhibit a new property resulting from the synergy between the core and shell of a coordination polymer heterostructure, giving direct evidence that the photomagnetic response of the shell is magnetomechanical in origin.
Journal ArticleDOI
Grafting of hydrophilic ethylene glycols or ethylenediamine on coordinatively unsaturated metal sites in MIL-100(Cr) for improved water adsorption characteristics
TL;DR: In this paper, the authors show that MIL-100(Cr)-EN is very promising as a water sorption material, e.g., for heat-transformation applications.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.