Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Tuning the electron transport of molecular junctions by chemically functionalizing anchoring groups: First-principles study
TL;DR: In this article, density-functional calculations of the electronic structures and electron transport properties of organic molecular junctions with several anchoring groups containing atoms with different electronegativities are presented.
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Application of two Cu(II)-azido based 1D coordination polymers in optoelectronic device: Structural characterization and experimental studies
TL;DR: In this paper, two new azido bridged 1D polymeric Cu(II) chains, [Cu(L1)(μ1,3-N3)]∞ (1) and [Cu2(L2)2(μ 1,1-n3)(μ 1 3 N3)-N3−) have been synthesized by using two different N2O donor tridentate reduced Schiff base ligands.
Journal ArticleDOI
Organic melt, electride, and CVD induced in situ deposition of luminescent lanthanide imidazolate MOFs on nanostructured alumina
Larissa V. Meyer,Joachim Vogt,Helmut Schäfer,Martin Steinhart,Rolf Böttcher,Andreas Pöppl,Marit Mai,Claus Feldmann,Klaus Müller-Buschbaum +8 more
TL;DR: In this article, three different growth processes unusual for MOFs were investigated and compared: a film growth process in situ to MOF formation from the linker melt, electride induction with solvated electrons, and chemical vapour deposition (CVD) to additionally utilize the gas phase.
Journal ArticleDOI
Molecular tectonics: homochiral coordination networks based on combinations of a chiral neutral tecton with Hg(II), Cu(II) or Ni(II) neutral complexes as metallatectons
TL;DR: The use of compound 1 as an enantiomerically pure neutral and rigid organic linear tecton bearing two divergently oriented monodentate coordinating sites appended with two chiral centres of the same (S) configuration leads, to the formation of four homochiral 1- and 2-D coordination polymers.
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Solvent induced synthesis, structure and properties of coordination polymers based on 5-hydroxyisophthalic acid as linker and 1,10-phenanthroline as auxiliary ligand
TL;DR: In this article, a single-crystal X-ray diffraction analysis reveals that all three coordination polymers 1, 2 and 3 crystallize in monoclinic space group P2/n.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.