Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
Citations
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Magnetic MOF microreactors for recyclable size-selective biocatalysis
TL;DR: Highly porous magnetic MOF microreactors can be prepared around a Pickering-stabilized hydrogel core, providing a facile means for the encapsulation of enzymes for size-selective biocatalysis.
Journal ArticleDOI
Application of Metal‐organic Frameworks
TL;DR: In this article, the potential and emerging applications of metal-−-organic frameworks and porous coordination polymers are discussed, and a mini-review is presented, focusing on the potential applications of these materials.
Journal ArticleDOI
High-yield, fluoride-free and large-scale synthesis of MIL-101(Cr)
Tian Zhao,Felix Jeremias,Felix Jeremias,Ishtvan Boldog,Binh D. Nguyen,Stefan K. Henninger,Christoph Janiak +6 more
TL;DR: The effect of inorganic and organic acid modifiers was thoroughly investigated in the synthesis of MIL-101(Cr) and HNO3 could increase the yield to over 80% of a product with average SBET > 3200 m(2) g(-1) in repeated experiments (from an average of 50% in most published syntheses) in small-scale laboratory synthesis.
Journal ArticleDOI
Zirconium-based metal organic frameworks: Highly selective adsorbents for removal of phosphate from water and urine
TL;DR: In this paper, a zirconium-based MOF, UiO-66, was selected as representative MOF given its exceptional stability in water and investigated the effect of an amine functional group.
Journal ArticleDOI
Single-Site Heterogeneous Catalysts for Olefin Polymerization Enabled by Cation Exchange in a Metal-Organic Framework.
TL;DR: It is shown that these new catalysts copolymerize ethylene and propylene, and reactivity approaches single-site catalysis, as evidenced by low polydispersity indices, and good molecular weight control.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.