Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Luminescent Functional Metal–Organic Frameworks
Journal ArticleDOI
Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites.
Norbert Stock,Shyam Biswas +1 more
Journal ArticleDOI
Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks
Jian-Rong Li,Yuguang Ma,M. Colin McCarthy,Julian P. Sculley,Jiamei Yu,Hae-Kwon Jeong,Perla B. Balbuena,Hong-Cai Zhou +7 more
TL;DR: In this article, the authors review the research progress in metal-organic frameworks (MOFs) for CO 2 adsorption, storage, and separations that are directly related to CO 2 capture.
Journal ArticleDOI
Metal Azolate Frameworks: From Crystal Engineering to Functional Materials
TL;DR: A comparison study of 3D Networks Based on Polypyrazolates, Metal 1,2,4-Triazolate Frameworks, and Univalent Coinage-Metal Tetrazolate Framework 1025.
Journal ArticleDOI
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions
TL;DR: In this review, the applications of MOFs with multiple active sites in synergistic organic catalysis, photocatalysis and tandem reactions are discussed and proposed mechanisms are presented in detail.
References
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Journal ArticleDOI
Unique gas and hydrocarbon adsorption in a highly porous metal-organic framework made of extended aliphatic ligands
TL;DR: High and unique gas and hydrocarbon adsorption in a highly stable guest-free microporous metal-organic framework constructed on rigid aliphatic ligands, H(2)bodc and ted, is reported in this work.
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Microporous networks co-assembled by both rigid and flexible building blocks
TL;DR: In this paper, the porous networks of [Cu2(malonato)2(bipy)(H2O)2]·H 2O (I) and [Cd(maloneato)(py)(H 2 O)] (II) were co-assembled by rigid 4,4′-bipyridine or pyridine and the flexible malonate ion.
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A zinc(II) coordination polymer constructed from mixed-ligand 1,2-bis(2-(1H-imidazol-1-yl)ethoxy)ethane and 1,4-benzenedicarboxylic acid
Yan Qi,Yun-Xia Che,Ji-Min Zheng +2 more
TL;DR: In this paper, an example of the 1,2-bis(2-(1 H-imidazol-1-yl)ethoxy)ethane (L) ligand, exhibiting an eight-connected 36·418·53·6 net with trinuclear zinc clusters as secondary building units.
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X-ray Crystal Structures, Electron Paramagnetic Resonance, and Magnetic Studies on Strongly Antiferromagnetically Coupled Mixed μ-Hydroxide-μ-N1,N2-Triazole-Bridged One Dimensional Linear Chain Copper(II) Complexes
TL;DR: Four new metal-organic polymeric complexes, synthesized in a reaction of substituted 1,2,4-triazole and various copper(II) salts in water/acetonitrile solutions, were discussed on the basis of complementarity/countercomplementarity of the two competing bridges.
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Synthesis, crystal structures and luminescence properties of lanthanide oxalatophosphonates with a three-dimensional framework structure
TL;DR: The lanthanide oxalatophosphonates have been synthesized under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction as well as by infrared spectroscopy, elemental analysis and thermogravimetric analysis as mentioned in this paper.