Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
Reads0
Chats0
TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
Citations
More filters
Journal ArticleDOI
Luminescent Functional Metal–Organic Frameworks
Journal ArticleDOI
Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites.
Norbert Stock,Shyam Biswas +1 more
Journal ArticleDOI
Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks
Jian-Rong Li,Yuguang Ma,M. Colin McCarthy,Julian P. Sculley,Jiamei Yu,Hae-Kwon Jeong,Perla B. Balbuena,Hong-Cai Zhou +7 more
TL;DR: In this article, the authors review the research progress in metal-organic frameworks (MOFs) for CO 2 adsorption, storage, and separations that are directly related to CO 2 capture.
Journal ArticleDOI
Metal Azolate Frameworks: From Crystal Engineering to Functional Materials
TL;DR: A comparison study of 3D Networks Based on Polypyrazolates, Metal 1,2,4-Triazolate Frameworks, and Univalent Coinage-Metal Tetrazolate Framework 1025.
Journal ArticleDOI
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions
TL;DR: In this review, the applications of MOFs with multiple active sites in synergistic organic catalysis, photocatalysis and tandem reactions are discussed and proposed mechanisms are presented in detail.
References
More filters
Journal ArticleDOI
Novel 2D and 3D Indium Metal-Organic Frameworks: Topology and Catalytic Properties†
Berta Gómez-Lor,Enrique Gutiérrez-Puebla,Marta Iglesias,Miguel Monge,and C. Ruiz-Valero,Natalia Snejko +5 more
TL;DR: In this paper, it was shown that while the metal/connector/chelate rate is 1:1:1, the introduction of a chelate ligand, such as bipy or phen, blocks the possibility of connections in one direction, inducting the formation of 2D structures.
Journal ArticleDOI
Polygons and Faceted Polyhedra and Nanoporous Networks.
TL;DR: Small rhombihexahedra and small cubicuboctahedra form the basis of two novel low-density framework solids that are afforded by the self-assembly of molecular squares only or molecular squares and triangles, respectively.
Journal ArticleDOI
Radical Polymerization of Vinyl Monomers in Porous Coordination Polymers: Nanochannel Size Effects on Reactivity, Molecular Weight, and Stereostructure
TL;DR: In this paper, the authors performed radical polymerization of vinyl monomers (styrene, methyl methacrylate, and vinyl acetate) in various nanochannels of porous coordination polymers (PCPs), where relationships between the channel size and polymerization behaviors, such as monomer reactivity, molecular weight and stereostructure, were studied.
Journal ArticleDOI
Supramolecular assemblies of trinuclear triangular copper(II) secondary building units through hydrogen bonds. Generation of different metal-organic frameworks, valuable catalysts for peroxidative oxidation of alkanes.
Corrado Di Nicola,Yauhen Yu. Karabach,Alexander M. Kirillov,Magda Monari,Luciano Pandolfo,Claudio Pettinari,Armando J. L. Pombeiro +6 more
TL;DR: Single-crystal X-ray molecular structure determinations show that both compounds have analogous trinuclear triangular structures, but very different supramolecular assemblies, due mainly, but not only, to the crystallization molecule of H2O in 1b.
Journal ArticleDOI
Chemistry and application of flexible porous coordination polymers
TL;DR: In this article, the chemistry and application of flexible crystalline polymers are summarized and discussed, and a review of their application in gas storage, gas separation and catalytic reaction is presented.