Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
Reads0
Chats0
TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
Citations
More filters
Journal ArticleDOI
Formation of Gold Nanoclusters from Goldcarbonyl Chloride inside the Metal-Organic Framework HKUST-1
TL;DR: In this article , small Aux clusters with an average atom number of x ≈ 5 are formed in the medium-sized pores of the HKUST-1 matrix, which are homogeneously distributed and crystallographically ordered.
Journal ArticleDOI
Synthesis and structural characterization of metal azolate/carboxylate frameworks incorporating the 1-H-pyrazol-3,4,5-tricarboxylate ligand
TL;DR: In this article , the metal azolate/carboxylate (MAC) frameworks are decomposed into 1-D chains alternating monomeric and dimeric units and a 3-D non-porous network.
Journal ArticleDOI
When Polymorphism in Metal-Organic Frameworks Enables Water Sorption Profile Tunability for Enhancing Heat Allocation and Water Harvesting Performance.
Tobie J. Matemb Ma Ntep,Mohammad Wahiduzzaman,Eric Laurenz,Ieuan Cornu,Georges Mouchaham,Iurii Dovgaliuk,Shyamapada Nandi,Klaus Knop,Christian Jansen,Farid Nouar,Pierre Florian,Gerrit Füldner,Guillaume Maurin,Christoph Janiak,Christian Serre +14 more
TL;DR: In this article , polymorphism in Al-metal-organic frameworks is disclosed as a new strategy to tune the hydrophilicity of MOFs, which involves the formation of a MOF built from chains of either trans- or cis-μ-OH-connected corner-sharing AlO4 (OH)2 octahedra.
Proceedings ArticleDOI
Fabrication of MIL-100 (Fe) metal-organic framework nanocarrier for the controlled release of Paclitaxel against MCF-7 breast cancer cells
TL;DR: In this article , the authors used MIL-100 (Fe) as a drug carrier for paclitaxel (PTX) to reduce the abuse side effects of PTX and enhance its efficacy through the controlled release of the PTX from MOF.
Journal ArticleDOI
Design of Coordination Polymers based on combinations of 1,2-diphenylethane-1,2-diyl diisonicotinate with Cu(II), Zn(II), Cd(II) and Co(II)
TL;DR: In this paper , the use of the flexible organic ligand L (1,2-Diphenylethane-1, 2-diyl diisonicotinate) combined with Cu(acac)2, Cu(hfac) 2, ZnCl2, CdI2 or CoCl2 was proposed.
References
More filters
Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.