Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Recent advances in Fe-based metal-organic frameworks derivatives for batteries applications
Yuze Zhang,Qianhong Huang,Jiawei Liu,Jianen Zhou,Xiao-Ming Lin,Akif Zeb,R. Chenna Krishna Reddy,Xuan Xu +7 more
TL;DR: In this paper , the authors developed rechargeable batteries with better electrochemical performance, especially when the traditional rechargeable battery is hard to be used and it has become necessary to develop rechargeable rechargeables with better performance.
Journal ArticleDOI
A first principles study of interactions of CO 2 with surfaces of a Cu(benzene‐1,3,5‐tricarboxylate) metal organic framework
TL;DR: In this paper, density functional theory is used to investigate the interaction of CO2 with the 100 and 010 surfaces of a Cu(benzene 1,3,5 tricarboxylate) metal organic framework.
Journal ArticleDOI
Efficient Diffusion-Controlled Ligand Exchange Crystal Growth of Isostructural Inorganic–Organic Halogenidorhodates(III): The Missing Hexaiodidorhodate(III) Anion
Maciej Bujak,Maciej Bujak +1 more
TL;DR: In this paper, a diffusion-controlled ligand exchange crystal growth method using a hydrochloric acid solution of rhodium(III) chloride trihydrate and piperazine, dissolved in hydrobromic and hydroiodic acid, respectively, separated by a layer of hydrohalic acid.
Reference EntryDOI
Metal‐Organic Frameworks: Fluorinated Frameworks
Pradip Pachfule,Rahul Banerjee +1 more
TL;DR: In this paper, it has been demonstrated that exposed fluorine-lined channels show affinity toward the gaseous molecules because of the high electronegativity of fluorine atoms.
Journal ArticleDOI
A Bridge Too Far: Testing the Limits of Polypyridyl Ligands in Bridging Soluble Subunits of a Coordination Polymer
Samuel V. F. Beddoe,Anthony J. Fitzpatrick,Anthony J. Fitzpatrick,Jason R. Price,Neil Mallo,Jonathon E. Beves,Grace G. Morgan,Jonathan A. Kitchen,Tony D. Keene,Tony D. Keene +9 more
TL;DR: In this paper, the identity and solution stability of the [Cu(L)] units have been investigated through a novel combined UV-vis/EPR experiment and it has been found to be a stable supramolecular building unit for the construction of discrete complexes and coordination polymers.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.