Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Thermal post-synthetic modification of Al-MIL-53–COOH: systematic investigation of the decarboxylation and condensation reaction
TL;DR: In this paper, the Al-MIL-53-COOH derivative was discovered under solvothermal conditions using a high-throughput set-up suitable for microwave (MW)-assisted heating.
Journal ArticleDOI
Investigation of Cross-Linked and Additive Containing Polymer Materials for Membranes with Improved Performance in Pervaporation and Gas Separation
Katharina Hunger,Nadine Schmeling,Harold B. Tanh Jeazet,Christoph Janiak,Claudia Staudt,Karl Kleinermanns +5 more
TL;DR: Pervaporation and gas separation performances of polymer membranes can be improved by crosslinking or addition of metal-organic frameworks (MOFs) and mixed-matrix membranes with MOFs as additives (fillers) have increased permeabilities and often also selectivities compared to the pure polymer.
Journal ArticleDOI
New silver BioMOFs driven by 1,3,5-triaza-7-phosphaadamantane-7-sulfide (PTAS): synthesis, topological analysis and antimicrobial activity
Sabina W. Jaros,Piotr Smoleński,M. Fátima C. Guedes da Silva,M. Fátima C. Guedes da Silva,Magdalena Florek,Jarosław Król,Zdzisław Staroniewicz,Armando J. L. Pombeiro,Alexander M. Kirillov +8 more
TL;DR: In this paper, two new bioactive silver-organic frameworks [Ag(μ3-PTAS)]n(NO3)n·nH2O (1) and [Ag4(μ4- PTAS)(μ5-PTAs)(μ2-SO4)2(H2Os)2]n·2nH 2O (2) were easily assembled, thus opening up the application of PTAS as a versatile N,S-building block in the crystal engineering of MOFs.
Journal ArticleDOI
MIL series of metal organic frameworks (MOFs) as novel adsorbents for heavy metals in water: A review.
Han Zhang,Xin Hu,Tianxiao Li,Yuxuan Zhang,Hongxia Xu,Yuanyuan Sun,Xueyuan Gu,Chenggang Gu,Jun Luo,Bin Gao +9 more
TL;DR: In this article , a review of recent progress in the synthesis and application of MIL-based adsorbents for the removal of aqueous heavy metal ions is presented, which outlines prospects and future directions to promote the applications of MILs in treating heavy metal contaminated water.
Journal ArticleDOI
A Rational Route to Coordination Polymers with Condensed Networks and Cooperative Magnetic Properties
TL;DR: In this paper, a rational route to coordination polymers that can show cooperative magnetic phenomena is presented, in which the metal cations are linked by the anionic ligands and the intermediates are formed in very pure form and in quantitative yields.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.