Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Luminescent Functional Metal–Organic Frameworks
Journal ArticleDOI
Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites.
Norbert Stock,Shyam Biswas +1 more
Journal ArticleDOI
Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks
Jian-Rong Li,Yuguang Ma,M. Colin McCarthy,Julian P. Sculley,Jiamei Yu,Hae-Kwon Jeong,Perla B. Balbuena,Hong-Cai Zhou +7 more
TL;DR: In this article, the authors review the research progress in metal-organic frameworks (MOFs) for CO 2 adsorption, storage, and separations that are directly related to CO 2 capture.
Journal ArticleDOI
Metal Azolate Frameworks: From Crystal Engineering to Functional Materials
TL;DR: A comparison study of 3D Networks Based on Polypyrazolates, Metal 1,2,4-Triazolate Frameworks, and Univalent Coinage-Metal Tetrazolate Framework 1025.
Journal ArticleDOI
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions
TL;DR: In this review, the applications of MOFs with multiple active sites in synergistic organic catalysis, photocatalysis and tandem reactions are discussed and proposed mechanisms are presented in detail.
References
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Journal ArticleDOI
Spacer Length Effect on the Photoinduced Electron Transfer Fluorescent Probe for Alkali Metal Ions
TL;DR: In this paper, the effect of spacer length on the emission properties of pyrene fluorophore upon complication of alkali metal ions by the crown moiety has been investigated and the maximum efficiency for PET between the pyrene moiety and aza-crown ether is achieved when n ≤ 3.
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Hysteretic sorption of light gases by a porous metal–organic framework containing tris(para-carboxylated) triphenylphosphine oxide
Simon M. Humphrey,Shaunt E. Oungoulian,Ji Woong Yoon,Young Kyu Hwang,Erica R. Wise,Jong San Chang +5 more
TL;DR: The porous metal-organic framework PCM-4, based on tris(para-carboxylated) triphenylphosphine oxide, contains atypical, polar organic substituents; the material exhibits a hysteretic sorption of Ar, N2 and O2, and demonstrates the advantage of ligands of this type.
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ZnO Nanoparticles From a Metal-Organic Framework Containing ZnII Metallacycles
TL;DR: In this paper, a ladder-like metal-organic framework was proposed to form wurtzite ZnO nanoparticles when heated above 600 °C. But it was shown that the structure of the ladder was not optimal.
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[NiL]3[BTC]2·14H2O [L = 3,10-bis(2-ethyl)-1,3,5,8,10,12-hexaazacyclotetradecane, BTC = 1,3,5-benzenetricarboxylate]: synthesis, structure and unique selective guest molecule absorption properties
TL;DR: In this paper, 1,3,5-benzenetricarboxylate with a macrocyclic Ni(II) complex leads to a porous metal-organic framework, which displays a high selectivity for ethanol sorption.
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Two novel manganese coordination polymers containing both double-stranded chain and single chain or double-stranded chain
TL;DR: In this paper, the reaction of bis(1,2,4-triazol-1-yl)ethane (bte), MnSO4·H2O with KNCS or NaN(CN)2 yields two novel polymers [Mn(gauche-bte)2(NCS)2]n·n·mn(anti-bTE)(H 2O)2 (NCS), which contains both double-stranded chain and single chain and both the gauche and anti conformations bte.