Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Electrochemical synthesis, characterization and application of a microstructure Cu3(BTC)2 metal organic framework for CO2 and CH4 separation
TL;DR: In this article, a microstructure Cu3(BTC)2 MOF was synthesized through electrochemical path and successfully employed for CO2 and CH4 adsorption, which was carried out by XRD, FE-SEM, TGA, FTIR and BET analyses.
Journal ArticleDOI
A review on g-C3N4 incorporated with organics for enhanced photocatalytic water splitting
TL;DR: In this paper, the morphology control of graphitic carbon nitride (g-C3N4) as a photocatalyst including nanorods, nanotubes, nanosheets, nanospheres, porous structures and other different tunable nanostructures, are systematically studied.
Journal ArticleDOI
Programming MIL-101Cr for selective and enhanced CO2 adsorption at low pressure by postsynthetic amine functionalization.
Anupam Khutia,Christoph Janiak +1 more
TL;DR: Large CO2 uptake capacities of amine-functionalized 4 and 5, coupled with high adsorption enthalpy, high selectivities and proven long-term water stability, make them suitable candidates for capturing CO2 at low pressure from gas mixtures including the use as a CO2 sorbent from moist air.
Journal ArticleDOI
Extended lead(II) architectures engineered via tetrel bonding interactions
Ghodrat Mahmoudi,Ennio Zangrando,Mariusz P. Mitoraj,Atash V. Gurbanov,Atash V. Gurbanov,Fedor I. Zubkov,Maryam Moosavifar,Irina A. Konyaeva,Alexander M. Kirillov,Damir A. Safin +9 more
TL;DR: In this paper, an equimolar one-pot reaction of PbX2 (X = NO3−, CH3COO−) salts with HLI and H2LII in MeOH at 60 °C in a branched tube apparatus leads to heteroleptic complexes.
Journal ArticleDOI
Nanoscale biocoordination polymers: novel materials from an old topic.
Yaling Liu,Zhiyong Tang +1 more
TL;DR: It can be anticipated that nanoscale biocoordination polymers will become a diverse and rapidly growing class of novel materials and potentially lead to a breakthrough in biological applications.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.